Aluminum is a lightweight, soft, low strength metal which can easily be cast, forged, machined, formed and welded. Unless alloyed with specific elements, it is suitable only in low temperature applications. Aluminum is light gray to silver in color, very bright when polished, and dull when oxidized. A fracture in aluminum sections shows a smooth, bright structure. Aluminum gives off no sparks in a spark test, and does not show red prior to melting. A heavy film of white oxide forms instantly on the molten surface. Its combination of light weight and high strength make aluminum the second most popular metal that is welded. Aluminum and aluminum alloys can be satisfactorily welded by metal-arc, carbon-arc, and other arc welding processes. The principal advantage of using arc welding processes is that a highly concentrated heating zone is obtained with the arc. For this reason, excessive expansion and distortion of the metal are prevented.
Aluminum Alloys. Many alloys of aluminum have been developed. It is important to know which alloy is to be welded. A system of four-digit numbers has been developed by the Aluminum Association, Inc., to designate the various wrought aluminum alloy types. This system of alloy groups, shown by table 7-20, is as follows:
2XXX series. Copper is the principal alloy in this group, which provides extremely high strength when properly heat treated. These alloys do not produce as good corrosion resistance and are often clad with pure aluminum or special-alloy aluminum. These alloys are used in the aircraft industry.
3XXX series. Manganese is the major alloying element in this group, which is non-heat-treatable. Manganese content is limited to about 1.5 percent. These alloys have moderate strength and are easily worked.
4XXX series. Silicon is the major alloying element in this group. It can be added in sufficient quantities to substantially reduce the melting point and is used for brazing alloys and welding electrodes. Most of the alloys in this group are non-heat-treatable.
5XXX series. Magnesium is the major alloying element of this group, which are alloys of medium strength. They possess good welding characteristics and good resistance to corrosion, but the amount of cold work should be limited.
6XXX series. Alloys in this group contain silicon and magnesium, which make them heat treatable. These alloys possess medium strength and good corrosion resistance.
7XXX series. Zinc is the major alloying element in this group. Magnesium is also included in most of these alloys. Together, they form a heat-treatable alloy of very high strength, which is used for aircraft frames.
Aluminum Welding Alloys. Aluminum possesses a number of properties that make welding it different than the welding of steels. These are: aluminum oxide surface coating; high thermal conductivity; high thermal expansion coefficient; low melting temperature; and the absence of color change as temperature approaches the melting point. The normal metallurgical factors that apply to other metals apply to aluminum as well.
Aluminum is an active metal which reacts with oxygen in the air to produce a hard, thin film of aluminum oxide on the surface. The melting point of aluminum oxide is approximately 3600°F (1982°C) which is almost three times the melting point of pure aluminum (1220°F (660°C)). In addition, this aluminum oxide film absorbs moisture from the air, particularly as it becomes thicker. Moisture is a source of hydrogen, which causes porosity in aluminum welds. Hydrogen may also come from oil, paint, and dirt in the weld area. It also comes from the oxide and foreign materials on the electrode or filler wire, as well as from the base metal. Hydrogen will enter the weld pool and is soluble in molten aluminum. As the aluminum solidifies, it will retain much less hydrogen. The hydrogen is rejected during solidification. With a rapid cooling rate, free hydrogen is retained within the weld and will cause porosity. Porosity will decrease weld strength and ductility, depending on the amount.
Aluminum and aluminum alloys should not be cleaned with caustic soda or cleaners with a pH above 10, as they may react chemically.
The aluminum oxide film must be removed prior to welding aluminum. If it is not completely removed, small particles of unmelted oxide will be trapped in the weld pool and will cause a reduction in ductility, lack of fusion, and possibly weld cracking.
When welding aluminum, the aluminum oxide can be removed by mechanical, chemical, or electrical means. Mechanical removal involves scraping with a sharp tool, sandpaper, wire brush (stainless steel), filing, or any other mechanical method. Chemical removal can be done in two ways. One is by use of cleaning solutions, either the etching types or the non-etching types. The non-etching types should be used only when starting with relatively clean parts, and are used in conjunction with other solvent cleaners. For better cleaning, the etching type solutions are recommended, but must be used with care. When dipping is employed, hot and cold rinsing is highly recommended. The etching type solutions are alkaline solutions. The time in the solution must be controlled so that too much etching does not occur.
Chemical cleaning includes the use of aluminum welding fluxes. Fluxes are used for gas welding, brazing, and soldering. The coating on covered aluminum electrodes also maintains fluxes for cleaning the base metal. Whenever etch cleaning or flux cleaning is used, the flux and alkaline etching materials must be completely removed from the weld area to avoid future corrosion.
The electrical oxide removal system uses cathodic bombardment. Cathodic bombardment occurs during the half cycle of alternating current gas tungsten arc welding when the electrode is positive (reverse polarity). This is an electrical phenomenon that actually blasts away the oxide coating to produce a clean surface. This is one of the reasons why AC gas tungsten arc welding is so popular for welding aluminum.
Since aluminum is so active chemically, the oxide film will immediately start to reform. The time of buildup is not extremely fast, but welds should be made after aluminum is cleaned within at least 8 hours for quality welding. If a longer time period occurs, the quality of the weld will decrease.
**Aluminum **has a high thermal conductivity and low melting temperature. It conducts heat three to five times as fast as steel, depending on the specific alloy. More heat must be put into the aluminum, even though the melting temperature of aluminum is less than half that of steel. Because of the high thermal conductivity, preheat is often used for welding thicker sections. If the temperature is too high or the time period is too long, weld joint strength in both heat-treated and work-hardened alloys may be diminished. The preheat for aluminum should not exceed 400°F (204°C), and the parts should not be held at that temperature longer than necessary. Because of the high heat conductivity, procedures should utilize higher speed welding processes using high heat input. Both the gas tungsten arc and the gas metal arc processes supply this requirement. The high heat conductivity of aluminum can be helpful, since the weld will solidify very quickly if heat is conducted away from the weld extremely fast. Along with surface tension, this helps hold the weld metal in position and makes all-position welding with gas tungsten arc and gas metal arc welding practical.
The thermal expansion of aluminum is twice that of steel. In addition, aluminum welds decrease about 6 percent in volume when solidifying from the molten state. This change in dimension may cause distortion and cracking.
The final reason welding aluminum is different from steels is that it does not exhibit color as it approaches its melting temperature until it is raised above the melting point, at which time it will glow a dull red. When soldering or brazing aluminum with a torch, flux is used. The flux will melt as the temperature of the base metal approaches the temperature required. The flux dries out first, and melts as the base metal reaches the correct working temperature. When torch welding aluminum with oxyacetylene or oxyhydrogen, the surface of the base metal will melt first and assume a characteristic wet and shiny appearance. (This aids in knowing when aluminum welding temperatures are reached.) When welding aluminum with gas tungsten arc or gas metal arc, color is not as important, because the weld is completed before the adjoining area melts.
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